Product ID:WHITE GELCOAT, GV42000
MSDS Date:12/31/1989
FSC:8030
NIIN:00N019327
MSDS Number: BLGND

FERRO CORPORATION

1301 N FLORA ST
PLYMOUTH, IN 46563
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 219-935-5131

Preparer: KKR

Cage: 0LG38

FERRO CORPORATION

SANTA BARBARA, CA 93117-3092 US

Telephone: 805-968-5000

Cage: 0LG38

SHOULD ALWAYS BE PREMIXED SEPARATELY INTO PROD.

RTECS: 9999999ZZ

ADD FULL LENGTH FACESHIELD TO GOGGLES .

RTECS: 9999999ZZ

STYRENE, MONOMER (SARA III)

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 32.71%

OSHA PEL 100 PPM

ACGIH TLV: S,50PPM/100STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 12%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

TALC (CONTAINING NO ASBESTOS)

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 15%

OSHA PEL 2 MG/M3 RDUST

ACGIH TLV: 2 MG/M3 RDUST; 9192

SILICA, AMORPHOUS FUMED (MFR CAS #7631-86-9)

CAS: 112945-52-5

RTECS: VV7310000

Fraction By Weight: 1.80%

OSHA PEL 6 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

METHYL METHACRYLATE (SARA III)

CAS: 80-62-6

RTECS: OZ5075000

Fraction By Weight: 3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETOACETIC ACID, METHYL ESTER; (METHYL ACETOACETATE).

CAS: 105-45-3

RTECS: AK5775000

Fraction By Weight: .10%

EXCESSIVE QTYS OF TALC CAN RESULT IN SCARRING OF

RTECS: 9999999ZZ

& PRLNGD EXPOS TO TITIANIUM DIOXIDE MAY LEAD TO PULM

RTECS: 9999999ZZ

IN RATS REVEALED SIGNIFICANT INCR IN BENIGN &

RTECS: 9999999ZZ

OBSERVED AT LOW LEVELS. NORMAL CLEARANCE MECH OF

RTECS: 9999999ZZ

CONTRIBUTED TO THE OCCURENCE OF CARCINOGENICITY.

RTECS: 9999999ZZ

NEVER GIVE ANYTHING BY MOUTH TO AN

RTECS: 9999999ZZ

(METAL ORGANICS SUCH AS COBALT OR ANALINE TYPE)

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE:CAN CAUSE SEVERE IRRIT W/BURNING
SENSATION. MAY CAUSE MECH IRRIT. SKIN:MAY CAUSE IRRIT, DERM. SKIN
ABSORPTION OF STYRENE CAN OCCUR TO SIGNIFICANTLY INCR OVEREXP FROM
OTHER ROUTES OF ENTRY. INHAL:O VEREXP TO STYRENE & MMA CAUSES IRRIT
TOALL PARTS OF RESP TRACT. HIGH LEVELS CAN CAUSE ANESTHETIC (EFTS
OVEREXP)
Explanation of Carcinogenicity:STYRENE: GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:EFTS & CNS DEPRESS. MAY BE FATAL AT
10,000 PPM STYRENE. ALLERGIC RESP REACTIONS MAY BE POSS. EXCESSIVE
EXPOS TO TALC MAY CAUSE BRONCHIAL IRRIT (BRONCH). MAY CAUSE MECH
IRRIT. INGEST: CAUSES G I IRRIT & WILL CONTRIBUTE TO SYS EFTS.
CHRONIC:PRLNGD/RPTD CONTACT MAY CAUSE DERM &/OR ALLERGIC REACTIONS.
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH PROMPTLY W/LOTS OF WATER FOR AT LEAST 15 MINUTES
AND GET MD IMMED. SKIN:WASH THOROUGHLY. SEE MD IF IRRIT IS PRESENT
OR PERSISTS. SKIN:WASH THORO. SEE MD IF IRRIT IS PRESENT OR
PERSISTS. INHA L:REMOVE TO VENT AREA. MAKE COMFORTABLYWARM BUT NOT
HOT, USE O2 OR ARTF RESP AS REQ. SEE MD IF IRRIT IS
PRESENT/PERSISTS. INGEST:CALL MD IMMED.ONLY INDUCE VOMIT AT
INSTRUCTIONS OF MD.(SEE ING 12)

Flash Point Method:TCC
Flash Point:85.0F,29.4C
Lower Limits:1.1%
Upper Limits:8.2%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:HIGHLY FLAMM. CAN POLYMERIZE WHEN HEATED.
SEALED CNTNRS CAN RUPTURE EXPLOSIVELY WHEN HEATED. COMUSTION CAN
PRODUCE TOX GASES. TREAT AS OIL FIRE. (SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA
AND MAINTAIN VENTILATION. USE DESCRIBED PROTECTIVE MEASURES. USE
ABSORBENT MATERIAL, SUCH AS CLAY OR SAND, TO COLLECT AND CONTAIN
FOR SALVAGE AND DISPOSA L.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLOSED CONTAINERS AWAY FROM
SUNLIGHT, HEAT, FLAMES & SPARKS. STORE BELOW 100F, 60-80F
PREFERRED. DO NOT STORE NEAR FOOD OR FEED.
Other Precautions:DO NOT CUT, PUNCTURE, OR WELD ON OR NEAR CNTNR. SINCE
EMPTY CNTNRS RETAIN PROD RESIDUE, CONTINUE TO FOLLOW PRECS & HNDLG
SHOWN ON MSDS. AVOID IMPROPER ADDITION OF PROMOTER &/OR CATALYST.
CONSULT PROD BULLETIN. PROMOTERS (SEE INGRED 13)

Respiratory Protection:IN THE ABSENCE OF PROPER VENTILATION USE NIOSH/
MSHA APPROVED RESPIRATOR.
Ventilation:VENTILATE TO MAINTAIN EXPOSURE BELOW PUBLISHED EXPOSURE
LIMITS. USE EXPLOSION PROOF MOTORS & WIRING.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOG, MAY(SEE ING 15)
Other Protective Equipment:EYE WASH STATION WITHIN 10 SECONDS OF WORK
STATION. WHERE SPLASH CAN OCCUR, USE AN APRON.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:VAPS ARE HEAVIER THAN AIR. CAN TRAVEL ALONG GROUND OR THROUGH
VENT SYS, BE IGNIT BY SPARKS/FLAMES/STATIC. WATER MAY BE USED TO
KEEP FIRE-EXPOSED CNTNRS COOL UNTIL FIRE IS OUT. EFTS OF OVEREX
P:PRLNGD OVEREXP CAN CAUST SYMPS OF NAUS, HDCH, VOMIT, LOSS OF
APPETITE, & GEN WEAKNESS. PRLNGD EXPOS TO (SEE INGRED 7)

HCC:F4
Vapor Density:HVR/AIR
Spec Gravity:1.3
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NONE
Appearance and Odor:LIQUID WITH STYRENE ODOR

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, PEROXIDES, AND OTHER OXIDIZING AGENTS.
Stability Condition to Avoid:CONSIDERED STABLE AT ROOM TEMPERATURE.
Hazardous Decomposition Products:OXIDES OF CARBON, TITANIUM AND
ALUMINUM; INCOMPLETELY BURNED HYDROCARBONS.
Conditions to Avoid Polymerization:SUNLIGHT, HEAT, FLAMES, SPARKS,
CONTAMINATION, PROLONGED STORAGE ABOVE 100F.

Waste Disposal Methods:PACKAGE IN DOT APPROVED CONTAINERS AND TRANSPORT
TO EPA APPROVED TREATMENT, STORAGE, AND DISPOSAL (TSO) FACILITY.
DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOAL, STATE AND FEDERAL
REGULATIONS .

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
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particular situation.